The Chemistry of Anilines, Part 1Zvi Rappoport John Wiley & Sons, 13.03.2007 - 1180 Seiten Aniline is the parent molecule of a vast family of aromatic amines. Since its discovery in 1826 it has become one of the hundred most important building blocks in chemistry. Aniline is used as an intermediate in many different fields of applications, such as isocyanates, rubber processing chemicals, dyes and pigments, agricultural chemicals and pharmaceuticals. The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series, this volume treats all aspects of this functional group. It contains chapters on the theoretical and computational foundations; on analytical and spectroscopical aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. |
Inhalt
| 75 | |
3 Structural chemistry of anilines | 167 |
4 Thermochemistry of anilines | 259 |
5 Mass spectrometry and gasphase chemistry of anilines | 293 |
6 NMR spectra of anilines | 347 |
7 Substituted anilines as solvatochromic probes | 373 |
8 Hydrogen bonds of anilines | 407 |
9 Synthesis of anilines | 455 |
12 Analytical aspects of aromatic amines | 639 |
13 Manufacture and uses of the anilines A vast array of processes and products | 715 |
14 The spectroscopy photophysics and photochemistry of anilines | 783 |
15 Toxicological and environmental aspects of anilines | 835 |
16 Electrochemistry of anilines | 871 |
17 Proton sponges | 931 |
| 1027 | |
| 1095 | |
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Häufige Begriffe und Wortgruppen
2-naphthylamine acceptor acid Acta adducts alkyl amino group ammonia analysis angle aniline aniline derivatives aqueous aromatic amines aryl amines aryl chlorides aryl halides azo dyes base benzene benzidine BINAP carbon carcinogenic catalyst catalyzed Chem chemical shifts Chemistry complexes compounds correlation corresponding coupling deprotonation dimer dissociation DMSO effect electron energy enthalpy of formation equation Figure fluorescence gas-phase hydrogen bond interaction intermediate intramolecular ionization isomeric isomers kJ mol−1 ligand manufacture Mass Spectrom Me2N NMe2 mechanism MeCN MeOH methyl molecular molecules N-arylation N-methylaniline N,N-dimethylaniline nitro nitrogen atom nucleophilic observed ortho oxidation peaks Perkin Trans phenol Phys polar polymers presence probes proton sponges radical cation reaction reagents rearrangement reduction reductive elimination reported ring Scheme solution solvatochromic solvent species spectra spectrum steric structure studied substituents synthesis Table temperature Tetrahedron Lett values yields