Chemistry of Arsenic, Antimony and BismuthN.C. Norman Springer Science & Business Media, 31.12.1997 - 484 Seiten This book provides a detailed, wide ranging and up-to-date review of all aspects of the chemistry of the elements arsenic, antimony and bismuth. The chapters are written by an international team of authors each of whom is both active and expert in their particular field. The coverage includes chapters on general properties and periodicity, the elements themselves, inorganic derivatives of the elements, co-ordination and solution chemistry, organocompounds, organotransition metal compounds, environmental and medicinal aspects and analytical methods. This volume will be of particular value to graduate and postgraduate chemists and materials scientists in both industry and academia who are concerned with any aspect of the chemistry of these three elements and will also be an essential addition to the reference section of any chemistry library. |
Inhalt
Arsenic antimony and bismuth some general properties and aspects of periodicity | ix |
Metallurgy of the elements | 35 |
Inorganic derivatives of the elements | 63 |
Coordination chemistry and solution chemistry | 155 |
Organoarsenic and organoantimony compounds synthesis properties and uses in organic transformations | 203 |
Organobismuth compounds synthesis properties and uses in organic transformations | 279 |
Organotransition metal compounds with element to transition metal bonds | 341 |
Environmental and medicinal chemistry of arsenic antimony and bismuth | 399 |
Analytical methods | 437 |
Häufige Begriffe und Wortgruppen
acid Acta Cryst alkyl Allg alloys Anal analysis Angew anion Anorg antimony antimony and bismuth antimony(III aqueous arsenic and antimony arsenic(III arsenic(V arsenite arsine aryl As₂O AsCl bismuth bismuth atom bismuth(III bismuthines bond angle bond lengths bridging cation centre Chem chemistry Chim chloride cluster complexes compounds containing coordination copper crystal structure Dalton Trans decomposes described determination dimeric donor electron example group 15 elements H₂O halides halogen Huttner hydride Inorg Lett ligands lone pair McAuliffe melting point methyl mineral molecular molecules Naturforsch obtained octahedral geometry orbital organoarsenic Organomet Organometallics oxidation oxygen p-block pentavalent Ph Ph phase phosphorus Phys pnictogen prepared pyramidal pyramidal geometry reaction reacts reagents ring salts samples SbCl shown in Scheme sodium soluble solution species stable stibines sulphide synthesis Table temperature tertiary tervalent Tetrahedron tion toxic transition metal trigonal bipyramidal triphenylbismuthine Vahrenkamp Whitmire X-ray yield ylides
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