Algebraic Theory of Molecules

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Oxford University Press, 12.01.1995 - 272 Seiten
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Algebraic Theory of Molecules presents a fresh look at the mathematics of wave functions that provide the theoretical underpinnings of molecular spectroscopy. Written by renowned authorities in the field, the book demonstrates the advantages of algebraic theory over the more conventional geometric approach to developing the formal quantum mechanics inherent in molecular spectroscopy. Many examples are provided that compare the algebraic and geometric methods, illustrating the relationship between the algebraic approach and current experiments. The authors develop their presentation from a basic level so as to enable newcomers to enter the field while providing enough details and concrete examples to serve as a reference for the expert. Chemical physicists, physical chemists, and spectroscopists will want to read this exciting new approach to molecular spectroscopy.
 

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Inhalt

Chapter 1 The Wave Mechanics of Diatomic Molecules
3
Chapter 2 Summary of Elements of Algebraic Theory
21
Chapter 3 Mechanics of Molecules
60
Chapter 4 Threebody Algebraic Theory
72
Chapter 5 FourBody Algebraic Theory
119
Chapter 6 ManyBody Algebraic Theory
133
Chapter 7 Classical Limit and Coordinate Representation
156
Chapter 8 Prologue to the Future
190
Properties of Lie Algebras
197
Coupling of Algebras
206
Hamiltonian Parameters
218
References
221
Index
239
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