Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds

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Barry M. Trost, M.F. Semmelhack, Ian Fleming
Elsevier, 1991 - 1299 Seiten
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Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
 

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Inhalt

Additions to CXBonds Part
1
Oxidation of Activated CH Bonds
2
Other CarbonCarbon Bond Forming Reactions
3
Lewis Acids
139
5
371
Protecting Groups
391
Nucleophilic Aromatic Substitutions
423
Nucleophilic Aromatic Substitutions
424
Polar Additions to Alkenes and Alkynes
552
Nonpolar Additions to Alkenes and Alkynes
715
Nonpolar Additions to Alkenes and Alkynes
716
Elimination Reactions
722
Volume 9
903
8
1031
Author Index
1169
Subject Index
1245

Functional Group Interconversion
483
4
541
Polar Additions to Alkenes and Alkynes
551
Reduction
1267
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