Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds

a,ẞ-unsaturated acceptor acetate acid acyl addition reactions adduct afford aldehydes alkenes alkyl alkynes allyl amines anion aromatic aryl arynes B. M. Trost benzene carbanions carbon carbonyl catalyst Chem Chemistry Chim chiral chloride CO₂Et CO₂H CO₂Me CO₂Me CO₂Me complexes compounds conjugate addition derivatives diastereoselectivity dienes double bond E. J. Corey electron electrophilic enolate enone equation equiv esters ether EtO₂C example formation give Grignard reagents halides halogen heteroatom Heterocycles HMPA hydroformylation hydrogen intermediate intramolecular isomer ketones ligand MeO₂C MeOH mercury(II metal method methyl Michael Michael addition nucleophiles Organomet Organometallics oxidation palladium Perkin Trans Ph Ph precursor radical cyclizations react reaction conditions reactive reduction regioselectivity ring salts Scheme SiMe3 SO₂Ph solvent SRN1 stereochemistry stereoselectivity steric substitution substrates syn addition synthesis synthetic temperature Tetrahedron Lett tin hydride tion undergo vinyl yield ОАс