Catalysis: An Integrated Approach
This book concentrates on industrially relevant reactions which are catalyzed by heterogeneous and homogeneous catalysts. Homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis using metallic and non-metallic solids. In both areas the high degree of sophistication of spectroscopic techniques and theoretical modelling has led to an enormous increase in our understanding at the molecular level. This holds for the kinetics of the reactions and the reactivities of the catalysts, as well as for the syntheses of the catalytic materials. The development of catalysis science since the first edition of this book has necessitated a thorough revision, including special chapters on biocatalysis, catalyst characterization and adsorption methods. The multidisciplinary nature of catalysis is reflected in the choice of a novel combination of basic disciplines which will be refreshing and inspiring to readers.
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PREPARATION OF SUPPORTED CATALYSTS
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acid active addition adsorbed adsorption alcohol alkene ammonia amount applied atoms become bismuth bond carbon Catal catalyst centre changes Chem chemical complex compounds concentration constant containing conversion coordination coverage cracking decreases dependence described determining discussed dissociation effect electron energy enzyme ethene example expression fermentation formation formed function give glucose heat heterogeneous higher homogeneous hydrocarbons hydroformylation hydrogen important increases industrial interaction intermediate involved isomerization kinetic lead ligands limited liquid lower material mechanism metal molecular molecule observed obtained occupied occur operation orbitals overall oxidation oxygen particles phase polymer present pressure promoters propene reactant reaction rate reactor reduction removal respect rhodium scheme selectivity shown shows species step structure studies substrate surface synthesis Table takes temperature transfer transition typical valence values vanadia zeolite