Modern Allene Chemistry, 2 Volume SetNorbert Krause, A. Stephen K. Hashmi Wiley, 10.12.2004 - 1143 Seiten In this two-volume handbook, the editors Norbert Krause and A. Stephen K. Hashmi present all the important aspects and facts related to this hot topic. The treatment covers the whole range from the synthesis and classification via reactions right up to possible applications in the synthesis of natural products and drugs. With their excellent contributions an international team of outstanding authors highlight the multifarious uses and classes of allenes, making this an indispensable work for every organic chemist. From the Table of Contents: SYNTHESIS OF ALLENES Synthesis of Allenes by Isomerization Reactions Metal-Mediated Synthesis of Allenes Transition-Metal-Catalyzed Synthesis of Allenes Enantioselective Synthesis of Allenes SPECIAL CLASSES OF ALLENES Allenic Hydrocarbons - Preparation and Use in Organic Synthesis Cyclic Allenes Acceptor-Substituted Allenes Donor-Substituted Allenes Synthesis and Reactions of Allenylmetal Reagents REACTIONS OF ALLENES Ionic Additions to Allenes Fundamentals and Application of Free Radical Addition to Allenes Cycloadditions of Allenes Cyclizations of Allenes Transitions-Metal-Catalyzed Cross Couplings of Allenes Transitions-Metal-Catalyzed Cycloisomerizations of Allenes Transition-Metal-Catalyzed Addition/Cycloadditions of Allenes Oxidation of Allenes APPLICATIONS Allenic Natural Products and Phamaceuticals Allenes in Natural Product Synthesis Enyne-Allenes |
Inhalt
Modern Allene Chemistry Edited by N Krause and A S K Hashmi | 51 |
Allenes in Natural Product Synthesis 1041 | 52 |
Transition MetalCatalyzed Synthesis of Allenes | 93 |
Urheberrecht | |
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Häufige Begriffe und Wortgruppen
1,2-cyclohexadiene 2]-cycloadducts acceptor-substituted acetates acid addition adducts aldehydes alkyl alkyne allenyl ketones allyl Angew asymmetric synthesis axially chiral bromide carbon atom carbonyl catalyst Chem Chemistry Chim chiral allene chloride co-workers CO2Et CO2Me compounds conjugated cuprate cyclic allenes cyclization cycloadditions derivatives diastereomers Diels-Alder Diels-Alder reaction diene dimerization diradical double bond DPIBF electrophiles enantiomerically enantioselective Engl enolate enynes esters ether example formation furan furnished Grignard reagents H H H heterocycles Hopf hydrocarbons intermediate intramolecular isomer isomerization J. A. Marshall kcal kcal mol¯¹ ketones Khim KOtBu Krause lithiated lithium Me3Si MeLi mixture nBuLi nucleophilic obtained oxidation palladium-catalyzed Ph Ph PPh2 precursors prepared presence propargyl alcohols protonation R1 H reactive rearrangement regioselectivity resulting ring closure silyl SiMe3 species stereoselective styrene substitution substrates synthesis of allenes temperature Tetra Tetrahedron Lett tion trapping vinylallenes yield Scheme