Metal Ions in Biological Systems: Volume 29: Biological Properties of Metal Alkyl DerivativesHelmut Sigel, Astrid Sigel CRC Press, 19.01.1993 - 496 Seiten This volume is devoted to the research area regarding the biological properties of metal alkyl derivatives, offering an authoritative account of this subject by 16 scientists. In 11 chapters, Biological Properties of Metal Alkyl Derivatives highlights, in detail, derivatives of germanium, tin, lead, arsenic, antimony, selenium, tellurium, cobalt (vitamin B12 derivatives) and nickel (coenzyme F430), including the role of (mainly) micro-organisms in their formation. The derivatives of indium, thallium, bismuth, various transition metals and mercury are also covered to some extent, as are those of the non-metals silicon, phosphorus and sulfur, and the haloperoxidase route of the biogenesis of halomethanes by fungi and plants. The properties of these alkyl derivatives, their biosynthesis, including mechanistic aspects, their appearance in waters (rivers, lakes, oceans) and sediments, and their physiological and toxic effects are summarized. |
Inhalt
INTRODUCTION | 4 |
Chapter | 6 |
METAL IONS AND CHELATING AGENTS IN ANTIVIRAL | 7 |
Chapter | 9 |
THE PROPERTIES OF BINUCLEAR COPPER CENTERS IN MODEL | 15 |
Chapter 1 | 18 |
Fumio Arai Department of Public Health St Marianna University | 27 |
Conclusions | 28 |
Pratt Department of Chemistry University of Surrey | 229 |
Chemistry | 232 |
B12 in Historical Perspective | 276 |
REDOX CHEMISTRY | 287 |
MethylCoenzyme M Reductase | 294 |
Analysis | 300 |
Biophysical Studies | 306 |
Out of print | 317 |
Chapter 2 | 37 |
Chapter 3 | 43 |
INTRODUCTION | 57 |
BIOGEOCHEMISTRY OF METHYLGERMANIUM SPECIES IN NATURAL WATERS | 79 |
Chapter 4 | 101 |
BIOLOGICAL PROPERTIES OF ALKYL DERIVATIVES OF LEAD | 137 |
377 | 157 |
METABOLISM OF ALKYL ARSENIC AND ANTIMONY COMPOUNDS | 161 |
69 | 168 |
43 | 179 |
Chapter 7 | 185 |
Erminio Marafante Commission of the European Communities Joint | 216 |
Methane Formation by Reaction of Ni 1 F430M with | 320 |
Possible Catalytic Mechanisms | 328 |
Exposure and Intoxication | 332 |
Chapter 10 | 339 |
Chapter 11 | 345 |
Mechanisms of Halomethane Biosynthesis | 363 |
Metabolic Role of CH3C1 in Fungi | 370 |
Other Possible Metabolic Roles for CH3C1 | 383 |
389 | |
SUBJECT INDEX | 419 |
Häufige Begriffe und Wortgruppen
absorption acid alkyl alkyl arsenic compounds alkyllead alkylselenides alkyltin anaerobic Anal antiknock agents antimony Appl Arakawa arsenic arsenobetaine atom bacteria Biochem biogeochemical cycle biological biomethylation Bu2SnCl2 cells CH3-Cbl Chem chemical chemistry Co-C bond Co(I Co(II coenzyme complexes concentrations coordination corrinoids detection dibutyltin DMAA dose effect electron elements Environ environmental enzyme Et,Pb excreted exposure formation gas chromatography germanium Industr inhibition inorganic arsenic ligand M. O. Andreae marine mechanism mercury metabolism metal methanogenic methylcobalamin methylgermanium mg/kg microbial microorganisms MMGe and DMGe natural ng/liter observed organic organolead organolead compounds Organomet organometallic compounds organometallic species organotin compounds oxidation P. J. Craig P. N. Froelich pathway Pb poisoning phospholipid production rats reaction redox reduced reported samples sediments selenate selenite selenium soil tellurium temperature tion TMAO total lead toxicity Toxicol trans effect trimethylarsine urinary urine volatile W. T. Frankenberger
Verweise auf dieses Buch
Frontiers in Biosensorics I: Fundamental Aspects F.W. Scheller,Florian Schubert,Jutta Fedrowitz Eingeschränkte Leseprobe - 1996 |