Laboratory Methods of Inorganic Chemistry

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J. Wiley & Sons, 1909 - 258 Seiten
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Inhalt

INTRODUCTORY REMARKS ON LABORATORY PRACTICE
1
CHAPTER I
9
PAGE
17
CHAPTER II
26
THE PASSIVE CONDITION 18 Passive Iron AMORPHOUS STATE
32
Amorphous Sulphur COLLOIDAL STATE
33
ADSORPTION COMPOUNDS
34
Colloidal Platinum according to Bredig
36
96
135
THIOACIDS AND THEIR SALTS
136
Barium Trithiocarbonate
137
Potassium Ferric Sulphide
138
Ammonium Copper Tetrasulphide
139
102
141
Potassium Titanium Fluoride
142
Ammonium Plumbic Chloride Lead Tetrachloride
143

Colloidal Antimony Sulphide
37
Adsorption of Iodine by Charcoal Adsorption Curve 23 Lanthanum Blue
38
Molybdenum Blue
39
Hydrogels as Semipermeable Membranes
42
CHAPTER III
44
Liquid Sulphur Dioxide Critical Point
49
Sulphur Trioxide by the Contact Process
51
Oxidation of Naphthalin with Sulphuric Acid
53
Nitrogen Dioxide
54
Chromic Oxide in the Dry Way from a Chromate
55
Cuprous Oxide from Fehlings Solution HYDRIDES 32 Cerium Hydride 33 Copper Hydride
56
ACIDS BASES AND SALTS
58
a Acids and Bases 34 Physicochemical Detection of Electrolytic Dissociation
61
Hydrobromic Acid
62
Thallous and Thallic Hydroxides
64
b Halogen Compounds 37 Cupric and Cuprous Bromides
65
Cuprous Chloride 39 Potassium Iodide
66
Barium Chloride from Witherite
67
Manganous Chloride from Waste Manganese Liquors 42 Anhydrous Ferric Chloride Preparation of Chlorine
68
Anhydrous Ferrous Chloride Preparation of Hydrogen Chloride
70
Anhydrous Chromium Trichloride
71
Sulphur Chloride S₂Cl
74
Chlorides of Phosphorus 47 Chlorides of Antimony
75
32 32 33 33 34 36 37 38 38 39 40
81
9 5 8 3 8 8 8 858 44 49 49 51 53
84
54
85
56
88
57
89
61
90
62
96
64
97
CHAPTER IV
99
RE222 65 65
101
66
102
67
103
68
106
70
108
72
111
73
113
b Oxyhalogen Acids and their Salts
114
Potassium Perchlorate
118
Iodic Acid and Iodic Anhydride Time Reaction
119
Potassium Iodate from Potassium Chlorate
120
Potassium Bromate and Potassium Bromide
121
Potassium Nitrate from Sodium Nitrate
122
Silver Nitrate
123
Bismuth Nitrate and Basic Bismuth Nitrate
124
Electrolytic Preparation of Potassium Permanganate
125
Barium Ferrate
126
Sulphuric Acid from Pyrite by the Chamber Process
128
88
129
Alum from Kaolin
130
Sodium Thiosulphate
131
Sodium Tetrathionate
132
Potassium Persulphate Electrolytically
133
f Carbonates
134
Potassium Lead Iodide
144
Addition Products of Complex Hydrometalcyanic Acids with Oxygen Compounds
145
Potassium Cobalticyanide
146
Cobaltous Salt of Hydromercurithiocyanic Acid
147
Cadmium Iodide Autocomplex Compound
148
NITRITO ACIDS AND THEIR SALTS
149
Potassium Tetranitritodiamminecobaltate
150
CONDENSED ACIDS AND THEIR SALTS
151
ORGANOCOMPLEX COMPOUNDS
152
Optical Rotation of Uranyl Lævomalate
153
CHAPTER V
155
AMMONIUM COMPOUNDS AND SUBSTITUTED AMMONIUM COMPOUNDS
156
Hydrazine Sulphate Monochloramine
158
Semicarbazide Hydrochloride
161
Millons Base
162
METALAMMONIA COMPOUNDS
163
Silverammonia Sulphate
169
Tetramminecupric Chloride
170
Hexamminenickelous Bromide
171
Chloropentamminecobaltic Chloride from the preceding
172
Chloropentamminecobaltic Chloride from Cobalt Carbonate
173
Sulphate and Nitrate of the Chloropentammine Series
174
Hexamminecobaltic Salts Luteocobalt Salts
175
Aquopentamminecobaltic Salts Roseocobalt Salts
176
Dibromotetramminecobaltic Bromide Dibrompraseo Salt
178
1 6Dinitritotetramminecobaltic Chloride Croseocobalt Salt
179
Comparison of the Isomeric Dinitritotetramminecobaltic Salts
180
Trinitritotriammine Cobalt
182
Tetrammineplatinous Chloroplatinite Green Salt of Magnus
184
Tetrammineplatinous Chloride
185
HYDRATES
186
MeltingPoint Maximum for Magnesium Nitrate Hexahydrate Eutectic Mixture of Barium Chloride Dihydrate and Water
189
Calcium Sulphate Hemihydrate
193
Hydrates of Sodium Sulphate Supersaturated Solutions
194
Transition Point of Sodium Sulphate
195
Isomeric Chromic Chloride Hydrates
197
CHAPTER VI
199
Pyrosulphuric Acid Chloride
202
Nitrosylsulphuric Acid
204
ESTERS
205
Ethyl Nitrate
206
Amyl Nitrite and Methyl Nitrite
207
Unsymmetrical Diethyl Sulphite
209
Triethyl Phosphate
210
Tetraethyl Silicate
211
Zinc Ethyl
212
Lead Tetraphenyl by Grignards Reagent Diphenyllead Iodide
213
Nickel Carbonyl
215
CHAPTER VII
217
Beryllium Hydroxide from Beryl
219
Basic Beryllium Acetate
220
Columbium and Tantalum Compounds from Columbite
221
Molybdenum Compounds from Molybdenite
222
Tungsten Compounds from Wolframite
227
Working up of Pitchblende and Testing for Radioactivity
229
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