Molecular Driving Forces: Statistical Thermodynamics in Chemistry and Biology

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Garland Science, 2003 - 666 Seiten
This text shows how many complex behaviors of molecules can result from a few simple physical processes. A central theme is the idea that simplistic models can give surprisingly accurate insights into the workings of the molecular world. Written in a clear and student-friendly style, the book gives an excellent introduction to the field for novices. It should also be useful to those who want to refresh their understanding of this important field, and those interested in seeing how physical principles can be applied to the study of problems in the chemical, biological, and material sciences. Furthermore, Molecular Driving Forces contains a number of features including: 449 carefully produced figures illustrating the subject matter; 178 worked examples in the chapters which explain the key concepts and show their practical applications; The text is mathematically self-contained, with 'mathematical toolkits' providing the required maths; Advanced material that might not be suitable for some elementary courses is clearly delineated in the text; End-of-chapter references and suggestions for further reading.
 

Inhalt

Averages Standard Deviations
17
Problems
24
Heat Work Energy
37
Appendix A Table of Constants
43
Appendix B Table of Units
55
Partial Derivatives
62
Entropy the Boltzmann Distribution Law
81
Index
95
35
325
Chemical Kinetics Transition States
341
Heat Was Thought to Be a Fluid
345
Summary
364
Coulombs Law
369
The Electrostatic Potential
387
Problems
403
Electrochemical Equilibria
409

Thermodynamic Driving Forces
105
Free Energies
131
Maxwells Relations Mixtures
153
Boltzmann Distribution Law
171
Statistical Mechanics of Simple Gases and Solids
193
Temperature Heat Capacity
221
Chemical Equilibria
235
Equilibria Between Liquids Solids and Gases
251
Solutions and Mixtures
267
Solvation and Transfers of Molecules Between Phases
279
1
286
13
294
Vector Calculus
301
21
310
Physical Kinetics
315
Series and Approximations
423
Intermolecular Interactions
449
Phase Transitions
467
Cooperativity
493
Adsorption Binding Catalysis
515
Multisite Cooperative Ligand Binding
533
Oxygen Binding to Hemoglobin
546
Model of McGhee and von Hippel
552
Summary
558
Water as a Solvent
577
Alcohols Constrict the Volumes of Aqueous Mixtures
586
Polymer Solutions
593
Dilution Entropy Drives Solute Partitioning into Polymers
605
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Autoren-Profil (2003)

Ken A. Dill is Professor of Pharmaceutical Chemistry and Biophysics at the University of California, San Francisco.

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