Reactive Intermediate ChemistryRobert A. Moss, Matthew S. Platz, Maitland Jones, Jr. John Wiley & Sons, 07.01.2004 - 1080 Seiten Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is:
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Inhalt
Carbocations | 4 |
Reactivity of Carbocations | 15 |
Carbocations 3 | 29 |
Conclusion and Outlook | 35 |
Crossing the Borderline Between | 44 |
Aliphatic Nucleophilic Substitution at Tertiary Carbon | 59 |
Conclusion and Outlook | 65 |
Carbanions | 70 |
Conclusion and Outlook | 261 |
Singlet Carbenes | 273 |
Stable Singlet Carbenes | 329 |
Triplet Carbenes | 375 |
Atomic Carbon | 463 |
Nitrenes | 501 |
Synthetic Carbene and Nitrene Chemistry | 561 |
Nitrenium Ions | 593 |
Carbanions | 74 |
Basicity of CarbanionsAcidity of Carbon Acids | 76 |
Reactivity | 97 |
Radicals | 122 |
Multistep Radical Reactions | 134 |
Elementary Radical Reactions | 140 |
Conclusion and Outlook | 157 |
Radicals 121 | 163 |
NonKekulé Molecules | 166 |
Electron Spin or Paramagnetic Resonance Spectroscopy in Matrices | 172 |
INTRODUCTION | 200 |
Organic Radical Ions | 206 |
Historical CommentsOrigins of Radical Ion Chemistry | 207 |
Radical Ion Structures | 214 |
Relationships with Other Intermediates | 234 |
Silylenes and Germylenes Stannylenes Plumbylenes | 651 |
Structures | 718 |
Structures of Strained Hydrocarbons | 724 |
Structures Stability | 728 |
Reactivity of Strained Hydrocarbons Toward External Reagents | 733 |
Arynes | 741 |
Matrix Isolation | 797 |
A Tool | 847 |
The Picosecond Realm | 873 |
Reactions on the Femtosecond Time Scale | 899 |
Potential Energy Surfaces and Reaction Dynamics | 925 |
The Partnership between Electronic Structure Calculations | 961 |
1005 | |
Häufige Begriffe und Wortgruppen
absorption acid addition adducts alkene alkyl Angew anion aromatic atom azide ion biradical C-H bonds calculations carbanion Chem chemical chemistry compounds computed cyclization cyclopropane decay derivatives diazo dimer diradical effect energy example excited experimental Figure formation formed function gas phase geometry hydrogen interaction intersystem crossing isotope kcal/mol kinetic laser lifetime M. S. Platz matrix isolation mechanism methods methyl methylene molecular molecules nitrene nitrenium ion nucleophilic nucleophilic substitution observed orbital pair Ph Ph phenylnitrene photochemical photolysis Phys polar precursor predicted proton pulse R. A. Moss radical cation radical ions rate constant react reaction reactive intermediates rearrangement resonance Scheme silylene singlet singlet carbene solution solvent solvolysis species spectra spectroscopy spectrum spin stability steric studies substituents substrate synthesis t-Bu temperature Tetrahedron Lett thermal tion transient transition trapping triplet triplet carbene vibrational W. T. Borden
Verweise auf dieses Buch
The Vocabulary and Concepts of Organic Chemistry Milton Orchin,Roger S. Macomber,Allan R. Pinhas,R. Marshall Wilson Eingeschränkte Leseprobe - 2005 |